The problem of not finding paccache was simple.
For some reason, I was not finding paccache (I do not recall if I even tried pacc+tab-completion, which would have given me paccache, and then which paccache).
The key was given by this comment (added as answer later), which indicated I already had paccache.
I might have required updating some databases (for sure, at least pkgfile, see below).
I first expected to find paccache in package paccache and then in package pacman-contrib, as a separate package from pacman.
But I found no pacman-contrib. I must have been searching the wrong way (or I have now some databases updated as compared to what I had a couple of days ago, I am not sure), since
$ pacman -Q pacman
pacman 5.1.2-2
$ pacman -Q pacman-contrib
pacman 5.1.2-2
And also,
$ pkgfile -s /usr/bin/paccache
error: No repo files found. Please run `pkgfile --update'.
$ pkgfile --update
:: Updating 3 repos...
download complete: msys [ 951.1 KiB 61.2K/s 2 remaining]
download complete: mingw32 [ 3.5 MiB 81.6K/s 1 remaining]
download complete: mingw64 [ 3.5 MiB 73.1K/s 0 remaining]
:: download complete in 49.44s < 8.0 MiB 165K/s 3 files >
:: waiting for 1 process to finish repacking repos...
$ pkgfile -s /usr/bin/paccache
msys/pacman
$ pacman -Qo paccache
/usr/bin/paccache is owned by pacman 5.1.2-2
As for how to use paccache once available, I did previously find several good links, including those posted by harrymc.
So everything is clear now, except for:
The (ambiguous?) description pacman vs. pacman-contrib.
Whether paccache is exactly equivalent to a fine-tuned way of replacing rm commands only.