In my situation, do I have to use the second formula to find near-field reactive region boundary?
The choice between the two equations you provide is determined by if the antenna is "electromagnetically short", so it isn't about if it is "very short" from a human's perspective of short, but rather how its length compares to the wavelength it emits. More specifically the equation $n_n = \lambda$, where $n_n$ is the radius of the near field, is used anytime the length of the antenna is less than half of the wavelength of the frequency it is transmitting. Note that the far-field is considered to be $n_f = 2\lambda$ where $n_f$ is the distance from the antenna where the far-field beings, so there is some area between these two where you are neither in the near-field or the far-field and instead expiernce effects of both.
2.45 GHz has a wavelength of 12cm. Since your antenna is 14 cm in length it is not "electromagnetically short" and as such would not use the above equation and instead would use what is called the Fraunhofer Distance which is governed by the following equation $n_n = \frac{2D^2}{\lambda}$.
If I have to harvest within the reactive field of the transmitting antenna, can I use a dipole antenna or do I have to use a coil?
Coils are basically space-efficient for interacting with the near-field, specifically the magnetic field. They wont be very good at transmitting or receiving far-field, but they will be optimal at interacting with near-field. A capacitor design would be similarly true for the electric field component of the near-field. So a dipole would be less efficient for the space it took up for either meanwhile a inductor or capacitor configuration or a combination of the two would be your best bet if your only interest is harvesting in the near-field. the more the better. You can actually think of a faraday cage as the capacitor version of this if it were to encase the antenna completely. then the usual grounding cable you would attach to it would instead be your power line where you siphon off the power. Since it would completely envelop the antenna it would be pretty effective too. But a series of coils would also be effective.
If I can use a dipole antenna within the reactive region for harvesting, how would I find its impedance?
You can use it, and it will harvest energy, but you'll just waste a lot of space and it wont be nearly as efficient. You wont even be able to harvest all the flux that passes through it as it will re-radiate any energy it harvests to a certain extent. So a dipole really isnt your best way to harvest at all. But if you do use it just make sure its an antenna tuned to the frequency of the transmission for best results. The exact impedance isnt really the important part in the dipole case. The impedance will matter, however, if your using a coil. In that case just calculate the cut off frequency of the coil and make sure your coil is ideally about 10x bigger than that. If you want to harvest even more energy use additional coils rather than a single bigger coil.
All the above equations and a bit of detail and references on them can be found on wikipedia here: https://en.wikipedia.org/wiki/Near_and_far_field#Regions_according_to_electromagnetic_length